Pollution characteristics and potential sources of heavy metals in wet deposition of Weizhou island in Beibu Gulf
GUO Zhao, XU Hao, LAI Weilin, ZHANG Chunhua, LIU Guoqiang, LAO Qibin
To understand the pollution characteristics and potential sources of dissolved heavy metals (Cu, Pb, Zn, Cd and As) in the atmospheric wet deposition of Weizhou island in the Beibu Gulf, the rainwater samples of Weizhou island were collected in February (winter), May (spring), August (summer) and October (Autumn) in 2018. The results show that the contents of Cu, Pb, Zn, Cd and As in wet deposition of Weizhou island were 0.6 ~ 4.3 μg L-1, 0.10~1.28 μg L-1, 9.48~99.3 μg L-1, 0.13~0.42 μg L-1 and 0.24 ~ 4.85 μg L-1, the average of 3.1, 0.50, 29.69, 0.29 and 0.89 μg L-1, respectively. The highest level of five heavy metals were found in autumn, followed by summer, while lower levels in spring and winter. Compared with other regions, the levels of some metals in Weizhou island was at a high value, and there was a certain pollution load. The highest deposition flux of the five heavy metalswere found in summer, followed by autumn and spring, and the lowest in winter. The annual deposition fluxes of Cu, Pb, Zn, Cd and As were 4.85, 0.77, 45.72, 0.45 and 1.37 mg m-2 a-1, respectively. According to the estimation of the road area of Weizhou island, the deposition of Cu, Pb, Zn, Cd and As were 0.12, 0.02, 1.14, 0.01 and 0.03 t a-1 respectively. The results of the correlation and principal component analysis showed that the wet deposition of heavy metals in Weizhou island was mainly affected by motor vehicle sources and industrial pollution sources.